PVC Profiles are prone to thermal deformation in high temperature environments. This is because the glass transition temperature (Tg) of PVC materials is low (usually between 70°C-85°C). After exceeding this temperature, the material will become soft or even lose shape stability. In order to avoid thermal deformation in high temperature environments, it is necessary to optimize from multiple aspects such as material formulation, production process and design. The following are specific solutions:
Material modification
Adding heat stabilizers
Function: Heat stabilizers can improve the stability of PVC at high temperatures and prevent the material from decomposing or softening.
Common types:
Calcium zinc stabilizer: environmentally friendly stabilizer, suitable for construction and home fields.
Organotin stabilizer: provides higher thermal stability and is suitable for high temperature environments.
Lead salt stabilizer (gradually eliminated): traditional stabilizer, excellent performance but not environmentally friendly.
Effect: By adding an appropriate amount of heat stabilizer, the softening process of PVC at high temperatures can be delayed.
Use high molecular weight PVC resin
Function: High molecular weight PVC resin has higher melt viscosity and better heat resistance.
Effect: Compared with low molecular weight PVC, high molecular weight PVC is less likely to deform at high temperatures.
Adding reinforcing fillers
Function: Adding inorganic fillers (such as calcium carbonate, talcum powder, glass fiber, etc.) can increase the rigidity and heat deformation temperature of PVC.
Effect: Reinforcing fillers can limit the movement of PVC molecular chains, thereby improving its resistance to heat deformation.
Blending modification
Function: Blending PVC with other heat-resistant polymers (such as acrylate copolymers, ABS, PMMA) can significantly improve heat resistance.
Effect: PVC profiles after blending modification can maintain shape stability at higher temperatures.
Process optimization
Extrusion process control
Function: Excessive temperature during extrusion may cause internal stress concentration, affecting the heat deformation performance of the final product.
Optimization measures:
Control the temperature of the heating zone of the extruder to avoid overheating.
Use progressive cooling to reduce internal stress.
Ensure that the mold design is reasonable to avoid weak points caused by uneven melt flow.
Multi-layer co-extrusion technology
Function: Multi-layer co-extrusion can use more heat-resistant materials on the outer layer, while the inner layer still retains the functionality of ordinary PVC.
Effect: The outer layer material can effectively resist high temperatures, thereby protecting the shape of the overall profile.
Surface coating treatment
Function: Applying a high-temperature resistant coating (such as fluorocarbon coating, silicon-based coating) on the surface of the PVC profile can form a heat insulation barrier.
Effect: The coating can reflect part of the heat and reduce the surface temperature of the profile.
Structural design optimization
Increase wall thickness
Function: Increasing the wall thickness of the profile can improve its rigidity and deformation resistance.
Effect: Thicker profiles can better maintain their shape at high temperatures.
Design reinforcement ribs
Function: Designing a reinforcement rib structure inside the profile can significantly improve its bending and deformation resistance.
Effect: The reinforcement ribs can disperse stress and reduce deformation caused by high temperature.
Multi-cavity structure design
Function: The multi-cavity structure can not only improve the thermal insulation performance, but also enhance the overall rigidity of the profile.
Effect: Multi-cavity design can reduce heat transfer while providing additional support.
Use environment control
Reserve thermal expansion gap during installation
Function: PVC profiles will expand thermally at high temperatures. If sufficient gap is not reserved during installation, it may cause extrusion deformation.
Measures:
Calculate and reserve appropriate gaps based on the thermal expansion coefficient of the material.
Use flexible connectors or elastic sealing strips to accommodate thermal expansion.
Avoid direct exposure to high temperature sources
Function: Try to avoid direct exposure of PVC profiles to high temperature environments (such as direct sunlight, near heat sources).
Measures:
In outdoor applications, use sunshades or thermal insulation films.
In industrial environments, avoid installing PVC profiles near high-temperature equipment.
Alternative material selection
If PVC profiles cannot meet the needs of a specific high-temperature environment, the following alternative materials can be considered:
UPVC (rigid polyvinyl chloride): Through modification, UPVC has higher heat resistance and rigidity.
CPVC (chlorinated polyvinyl chloride): CPVC has significantly better heat resistance than ordinary PVC and can be used for a long time in environments above 100°C.
Composite materials: such as PVC and glass fiber composite materials, which have both heat resistance and high strength.
By combining these methods, the stability and service life of PVC profiles in high temperature environments can be significantly improved.